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• Aizen Sousuke

Complete Part C 100%.

• Don Kanonji

Complete Part C 100%.

• Goteitaishi

Complete Story Mode A-D with 100% on any difficulty.

• Grandfisher

Complete Story Mode A-D with 100% on any difficulty.

• Ichimaru Gin

Complete Part B 100%.

• Iduru Kira

Beat him in the Story Mode, in a level where you face him and Rangiku.

• Kukaku

Complete Part B 100%.

• Kyugohanin

Complete Story Mode A-D with 100% on any difficulty.

• Menos-Grande

Complete Story Mode A-D with 100% on any difficulty.

• Ogihci

Complete Part C 100%.

• Rangiku Matsumoto

Beat her in the Story Mode, in a level where you face her and Iduru.

• Ririn

Complete Part C 100%.

• Rukia Kuchiki

Beat the first part of the Story Mode.

• Shibata

Complete Story Mode A-D with 100% on any difficulty.

• Shrieker

Complete Story Mode A-D with 100% on any difficulty.

• Shuhei Hisagi

Beat him in the Story Mode.

• Soifon

Beat her in the Story Mode.

• Tatsuki

Complete Part C 100%.

• Tosen

Complete Part A 100%.

• Tsukaima

Complete Story Mode A-D with 100% on any difficulty.

• Ururu

Complete Part A 100%.

• Yachiru Kusajishi

Beat her in the Story Mode.