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• Unlock Big Wheel

Keep choosing the bad choice when you asked by computer (after beating Tinkerer).
[Report]

• Unlock Black Cat

Choose to save Black cat when you fight her (pick the 1st choice when asked by Smythe).
[Report]

• Unlock Hobgoblin

Keep choosing the bad choice (the 2nd/3rd choice) before fighting Kraven.
[Report]

• Unlock Jessica Drew

Choose to help Shield crew from the symbiote (before you fight with Jessica Drew).
[Report]

• Unlock Luke Cage

Make the bad choice (2nd choice) when you asked by a man who say he can divert the train containing symbiote.
[Report]

• Unlock Random Assist

You can get mysterio, Night Crawler, Wolverine, Ctylok, Galactus, Hypno Hustler randomly by beating any level or buying the ultra rare powe ups.
[Report]

• Unlock Shocker

Choose to free Shocker after defeating him.
[Report]

• Unlock Solidarity

Bring shocker to jail (after beating him).
[Report]

• Unlock Storm

Keep choosing the good answer when you asked by computer after defeating Tinkerer.
[Report]

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• Bookmark or Share Spider-Man: Web of Shadows

Bookmark or Share Spider-Man: Web of Shadows on PlayStation 2