Barbossa
Complete Shipreck City in Story mode.

Block all attacks
At the start menu press Triangle, Square, Triangle, Circle, Circle, Square and you'll block all the attacks.

Characters
Successfully complete the indicated task to unlock the corresponding character:

Ammand The Corsair: Successfully complete the Pirate Poker sub-mission in the Shipwreck City level.
Black Bart: Successfully complete the Combat Challenge in the Maelstrom level.
Bootstrap Bill Turner: Successfully complete the Defeat Enemies sub-mission in the Prison Fortress level.
Cannon Arm: Successfully complete the Combat Challenge in the Pearl vs. Kraken level.
Capitain Chevalle: Successfully complete the Port Royal level.
Captain Barbossa: Successfully complete the Shipwreck City level.
Captain Elizabeth Swann: Successfully complete the Combo Challenge in the Davy Jones Locker level.
Captain Jack Sparrow: Successfully complete the Prison Fortress level.
Captain Sao Feng: Successfully complete the Singapore level.
Captain Teauge: Successfully complete the Combat Challenge in the Prison Fortress level.
Cotton: Successfully complete the Rescue sub-mission in the Isla de Pelegostos level.
Davy Jones: Successfully complete Pearl vs. Dutchman level.
Elizabeth Swann: Successfully complete the Tortuga level.
Gentlemen Jocard: Successfully complete the Davy Jones Locker level.
Gibbs: Successfully complete the Combat Challenge in the Port Royal level.
Governor Swann: Successfully complete the Combat Challenge in the Pearl vs. Dutchman level.
James Norrington: Successfully complete the Combat Challenge in the Tortuga level.
Lian: Successfully complete the Combat Challenge in the Singapore level.
Lord Cuttler Beckett: Successfully complete the Maelstrom level.
Mercer: Successfully complete the Hit-Combo sub-mission in the Singapore level.
Mistress Ching: Successfully complete the Jackanism in the Tortuga level.
Mordillah: Successfully complete the Combo Challenge in the Prison Fortress level.
Pintel: Successfully complete the Isla Cruces level.
Ragetti: Successfully complete the Combat Challenge in the Isla Cruces level.
Sri Sumba Jee: Successfully complete the Combat Challenge in the Shipwreck City level.
Tai Huang: Successfully complete the Sea Battle level.
Tia Dalma: Successfully complete the Missing Person sub-mission in the Port Royal level.
Villanueva: Successfully complete the Combo Challenge in the Tortuga level.
Will Turner: Successfully complete the Isla de Pelegostos level.

Gold bars in Shipwreck City
This is the only level where you must go over an area twice to find the items. After you receive the captain's Piece Of 8 from the thief, you must go back over the area you traveled along to get to the thief (i.e. cut loose the rafts again and jump across). The second time you travel along this path, the gold bars will appear.

Invincibility
Hold L2 and R2 and press X, Triangle, Triangle, Square, L1, R1.

Isla Cruces level: Gold Idol location
When you get to the waterfall where enemies attack you, defeat them all. Then, walk into the waterfall. Behind the waterfall is a secret room with the gold idol.

Swords
The following swords are listed by order of strength. Complete the indicated task to unlock the corresponding sword.

Code - Effect

Bone sword - Complete the Davy Jones' Locker level
Cutlass - Default sword
Davy Jones' sword - Complete the Maelstrom level
Dutchman sword - Complete the Pearl Vs Dutchman level
Ghost sword - Complete the Hit Combo sub-mission on the Isla Cruces level
Gun sword - Complete the Sea Battle level
Legend sword - Complete the Hit Combo sub-mission on the Maelstrom level
Norrington sword - Complete the Isla Cruces level
Pirate King's sword - Complete the Shipwreck City level

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